The Seachem Flourish Iron Water Conditioner for Fish Tanks is a ferrous iron gluconate supplement with a high concentration (10,000 mg/L). It is specially designed for aquariums with plants. Plants can benefit from Flourish Iron much more easily because ferrous iron gluconate is already in the ferrous form, so they don't have to expend energy reducing it. Contrary to what other manufacturers may claim, gluconate is not toxic to plants or fish. In fact, due to the relatively weaker iron-gluconate bonding compared to iron-EDTA bonding, ferrous gluconate is better suited to foliar feeding than iron-EDTA. Furthermore, ferrous gluconate has the added benefit of being a carbon source.
Iron is immobile in plants. This means that plants cannot divert iron from older to newer leaves. As a result, deficiency symptoms appear first on new or young leaves. Because plants use iron to produce chlorophyll, a lack of iron causes chlorosis or yellowing of the younger leaves. Stems can also be short and slender. If the deficiency is severe and prolonged, each new leaf emerges lighter in color than the previous leaf.
When selecting an iron supplement, it is critical to understand the distinction between the two types of iron. The iron will be in one of two oxidation states: ferrous (+2 charge) or ferric (+3 charge). The preferred iron form is ferrous iron, which is soluble in water at any pH. Ferric iron, on the other hand, is only soluble below a pH of around 5.5; if the pH is higher than 5.5, which is more likely in a planted aquarium, the ferric iron will become insoluble and precipitate, settling in the root zone. Foliar absorption is rendered impossible once this occurs.